A Comprehensive Review on Green Synthesis of ZnO Nano Particles and its Applications in Photocatalysis
DOI:
https://doi.org/10.69968/ijisem.2025v4i2359-367Keywords:
Metal oxide, Water pollution, Photocatalytic process, Green synthesis, Advanced oxidation processes (AOPs), Zinc oxide nanoparticle (ZnO NPs)Abstract
One of the biggest issues facing humanity globally is water pollution. The discharge of untreated wastewater from urbanisation and population growth poses a serious danger to natural water supplies. Metal oxide is one of the most often used photosensitive catalysts in the photocatalysis process, which breaks down pollutants. Instead of using metal oxide in its bulk form, nanosized metal oxide is being employed to boost the photocatalytic activity. This review highlights the significant potential of green-synthesized ZnO nanoparticles (ZnO NPs) in photocatalytic applications. Various plant-based methods, including the use of brinjal calyxes and rosin from Pinus latteri, have demonstrated eco-friendly, low-cost, and efficient routes for ZnO NP synthesis. Overall, green synthesis offers a sustainable alternative to conventional chemical methods, producing highly active and environmentally benign nano catalysts. This makes green-synthesized ZnO NPs as promising candidates for wastewater treatment and broader environmental remediation efforts.
References
[1] G. A. Kaningini, S. Azizi, H. Nyoni, F. N. Mudau, K. C. Mohale, and M. Maaza, "Green synthesis and characterization of zinc oxide nanoparticles using bush tea (Athrixia phylicoides DC) natural extract: Assessment of the synthesis process.," F1000Research, vol. 10, pp. 1-21, 2022,https://doi.org/10.12688/f1000research.73272.4
[2] Eleen Dayana Mohamed Isa, Kamyar Shameli, Nurfatehah Wahyuny Che Jusoh, Siti Nur Amalina Mohamad Sukri, and Nur'Afini Ismail, "Photocatalytic Degradation with Green Synthesized Metal Oxide Nanoparticles - A Mini Review," J. Res. Nanosci. Nanotechnol., vol. 2, no. 1, pp. 70-81, 2021,https://doi.org/10.37934/jrnn.2.1.7081
[3] D. V. Pathak, "Photocatalytic Degradation of Emerging Contaminants in Water," Int. J. Innov. Sci. Eng. Manag., vol. 3, no. 3, 2024,https://doi.org/10.3390/toxics13020080
[4] Y. Bin Chan et al., "Green synthesis of ZnO nanoparticles using the mangosteen (Garcinia mangostana L.) leaf extract: Comparative preliminary in vitro antibacterial study," Green Process. Synth., vol. 13, no. 1, pp. 1-20, 2024,https://doi.org/10.1515/gps-2023-0251
[5] Y. S. Jara, "A Review on the Green Synthesis and Photocatalytic Applications of Pure, Doped and Codoped CuO Nanoparticles," Res. gate, no. March, 2023, doi: 10.13140/RG.2.2.34406.40005.
[6] J. Xu, Y. Huang, S. Zhu, N. Abbes, X. Jing, and L. Zhang, "A review of the green synthesis of ZnO nanoparticles using plant extracts and their prospects for application in antibacterial textiles," J. Eng. Fiber. Fabr., vol. 16, 2021,https://doi.org/10.1177/15589250211046242
[7] R. R. Gandhi and D. K. Koche, "An Insight of Zinc Oxide Nanoparticles (ZnO NPs): Green Synthesis, Characteristics and Agricultural Applications," Biosci. Biotechnol. Res. ASIA, vol. 21, no. September, pp. 863-876, 2024.https://doi.org/10.13005/bbra/3270
[8] U. Wijesinghe, G. Thiripuranathar, F. Menaa, H. Iqbal, A. Razzaq, and H. Almukhlifi, "Green synthesis, structural characterization and photocatalytic applications of ZnO nanoconjugates using Heliotropium indicum," Catalysts, vol. 11, no. 7, 2021,
https://doi.org/10.3390/catal11070831
[9] A. A. Fazil, S. Narayanan, M. S. Begum, G. Manikandan, and M. Yuvashree, "Green synthesis strategy for producing doped and undoped ZnO nanoparticles: their photocatalytic studies for industrial dye degradation," Water Sci. Technol., vol. 84, no. 10-11, pp. 2958-2967, 2021,https://doi.org/10.2166/wst.2021.308
[10] S. Raha and M. Ahmaruzzaman, "ZnO nanostructured materials and their potential applications: progress, challenges and perspectives," Nanoscale Adv., vol. 4, no. 8, pp. 1868-1925, 2022,https://doi.org/10.1039/D1NA00880C
[11] M. Mahajan et al., "Green synthesis of ZnO nanoparticles using Justicia adhatoda for photocatalytic degradation of malachite green and reduction of 4-nitrophenol," RSC Adv., vol. 15, no. 4, pp. 2958-2980, 2025,https://doi.org/10.1039/D4RA08632E
[12] S. Faisal et al., "Green Synthesis of Zinc Oxide (ZnO) Nanoparticles Using Aqueous Fruit Extracts of Myristica fragrans: Their Characterizations and Biological and Environmental Applications," ACS Omega, vol. 6, no. 14, pp. 9709-9722, 2021,https://doi.org/10.1021/acsomega.1c00310
[13] P. G. Krishna et al., "Photocatalytic Activity Induced by Metal Nanoparticles Synthesized by Sustainable Approaches: A Comprehensive Review," Front. Chem., vol. 10, no. September, pp. 1-21, 2022,https://doi.org/10.3389/fchem.2022.917831
[14] V. T. T. Nhu, N. D. Dat, L. M. Tam, and N. H. Phuong, "Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application," Beilstein J. Nanotechnol., vol. 13, pp. 1108-1119, 2022,https://doi.org/10.3762/bjnano.13.94
[15] H. Jan et al., "Biogenic Synthesis and Characterization of Antimicrobial and Antiparasitic Zinc Oxide (ZnO) Nanoparticles Using Aqueous Extracts of the Himalayan Columbine (Aquilegia pubiflora)," Front. Mater., vol. 7, no. August, pp. 1-14, 2020,https://doi.org/10.3389/fmats.2020.00249
[16] S. Fakhari, M. Jamzad, and H. Kabiri Fard, "Green synthesis of zinc oxide nanoparticles: a comparison," Green Chem. Lett. Rev., vol. 12, no. 1, pp. 19-24, 2019,https://doi.org/10.1080/17518253.2018.1547925
[17] J. Osuntokun, D. C. Onwudiwe, and E. E. Ebenso, "Green synthesis of ZnO nanoparticles using aqueous Brassica oleracea L. var. italica and the photocatalytic activity," Green Chem. Lett. Rev., vol. 12, no. 4, pp. 444-457, 2019,https://doi.org/10.1080/17518253.2019.1687761
[18] S. S. M. Hassan, W. I. M. E. Azab, H. R. Ali, and M. S. M. Mansour, "Green synthesis and characterization of ZnO nanoparticles for photocatalytic degradation of anthracene," Adv. Nat. Sci. Nanosci. Nanotechnol., vol. 6, no. 4, 2015,https://doi.org/10.1088/2043-6262/6/4/045012
[19] A. Fouda et al., "Green Synthesis of Zinc Oxide Nanoparticles Using an Aqueous Extract of Punica granatum for Antimicrobial and Catalytic Activity," J. Funct. Biomater., vol. 14, no. 4, 2023,https://doi.org/10.3390/jfb14040205
[20] N. T. Nguyen and V. A. Nguyen, "Synthesis, Characterization, and Photocatalytic Activity of ZnO Nanomaterials Prepared by a Green, Nonchemical Route," J. Nanomater., vol. 2020, 2020,https://doi.org/10.1155/2020/1768371
[21] M. A. Fagier, "Plant-Mediated Biosynthesis and Photocatalysis Activities ofZinc Oxide Nanoparticles: A Prospect towards Dyes Mineralization," J. Nanotechnol., 2021.https://doi.org/10.1155/2021/6629180
[22] G. Kamarajan, D. Benny Anburaj, V. Porkalai, A. Muthuvel, G. Nedunchezhian, and N. Mahendran, "Green synthesis of ZnO nanoparticles and their photocatalyst degradation and antibacterial activity," J. Water Environ. Nanotechnol., vol. 7, no. 2, pp. 180-193, 2022, doi: 10.22090/jwent.2022.02.006.
[23] A. A. Meji, D. Usha, and B. M. Ashwin, "Microwave-assisted green synthesis of zinc oxide nanoparticles using pistia stratiotes for anticancer and antibacterial applications," Mater. Res. Express, vol. 11, no. 8, 2024,https://doi.org/10.1088/2053-1591/ad6d34
[24] S. N. A. Mohamad Sukri, K. Shameli, E. D. Mohamed Isa, and N. A. Ismail, "Green Synthesis of Zinc Oxide-Based Nanomaterials for Photocatalytic Studies: A Mini Review," IOP Conf. Ser. Mater. Sci. Eng., vol. 1051, no. 1, p. 012083, 2021,https://doi.org/10.1088/1757-899X/1051/1/012083
[25] S. S. Wagh et al., "Comparative Studies on Synthesis, Characterization and Photocatalytic Activity of Ag Doped ZnO Nanoparticles," ACS Omega, vol. 8, no. 8, pp. 7779-7790, 2023,https://doi.org/10.1021/acsomega.2c07499
[26] F. Rahman et al., "Green synthesis of zinc oxide nanoparticles using Cocos nucifera leaf extract: characterization, antimicrobial, antioxidant and photocatalytic activity," R. Soc. Open Sci., vol. 9, no. 11, 2022,https://doi.org/10.1098/rsos.220858
[27] J. Singh, T. Dutta, K. H. Kim, M. Rawat, P. Samddar, and P. Kumar, "'Green' synthesis of metals and their oxide nanoparticles: Applications for environmental remediation," J. Nanobiotechnology, vol. 16, no. 1, pp. 1-24, 2018,https://doi.org/10.1186/s12951-018-0408-4
[28] A. M. El-Khawaga et al., "Green synthesized ZnO nanoparticles by Saccharomyces cerevisiae and their antibacterial activity and photocatalytic degradation," Biomass Convers. Biorefinery, pp. 2673-2684, 2025,https://doi.org/10.1007/s13399-023-04827-0
[29] H. Mohd Yusof, R. Mohamad, U. H. Zaidan, and N. A. Abdul Rahman, "Microbial synthesis of zinc oxide nanoparticles and their potential application as an antimicrobial agent and a feed supplement in animal industry: A review," J. Anim. Sci. Biotechnol., vol. 10, no. 1, pp. 1-22, 2019,https://doi.org/10.1186/s40104-019-0368-z
[30] A. E. Alprol, A. Eleryan, A. Abouelwafa, A. M. Gad, and T. M. Hamad, "Green synthesis of zinc oxide nanoparticles using Padina pavonica extract for efficient photocatalytic removal of methylene blue," Sci. Rep., vol. 14, no. 1, pp. 1-23, 2024,https://doi.org/10.1038/s41598-024-80757-9
[31] M. Khan, P. Ware, and N. Shimpi, "Synthesis of ZnO nanoparticles using peels of Passiflora foetida and study of its activity as an efficient catalyst for the degradation of hazardous organic dye," SN Appl. Sci., vol. 3, no. 5, pp. 1-17, 2021,https://doi.org/10.1007/s42452-021-04436-4
[32] A. Meji, M. U. D. B. M. Ashwin, A. Yardily, and M. S. Dennison, "Microwave ‑ assisted green synthesized ZnO nanoparticles : an experimental and computational investigation," Discov. Appl. Sci., 2025,https://doi.org/10.1007/s42452-025-06563-8
[33] A. S. Al Rahbi et al., "Green synthesis of zinc oxide nanoparticles from Salvadora persica leaf extract: Characterization and studying methyl orange removal by adsorption," Water Pract. Technol., vol. 19, no. 4, pp. 1219-1231, 2024,https://doi.org/10.2166/wpt.2024.042
[34] Y. Ounis Dkhil, T. Peppel, M. Sebek, J. Strunk, and A. Houas, "Green Synthesis of Photocatalytically Active ZnO Nanoparticles Using Chia Seed Extract and Mechanistic Elucidation of the Photodegradation of Diclofenac and p-Nitrophenol," Catalysts, vol. 15, no. 1, 2025,https://doi.org/10.3390/catal15010004
[35] S. Redjili et al., "Green Innovation: Multifunctional Zinc Oxide Nanoparticles Synthesized Using Quercus robur for Photocatalytic Performance, Environmental, and Antimicrobial Applications," Catalysts, vol. 15, no. 3, pp. 1-35, 2025,https://doi.org/10.3390/catal15030256
[36] Z. U. Zango et al., "A state-of-the-art review on green synthesis and modifications of ZnO nanoparticles for organic pollutants decomposition and CO2 conversion," J. Hazard. Mater. Adv., vol. 17, no. September 2024, p. 100588, 2025,https://doi.org/10.1016/j.hazadv.2024.100588
[37] B. Avinash et al., "Facile green synthesis of zinc oxide nanoparticles: Its photocatalytic and electrochemical sensor for the determination of paracetamol and D-glucose," Environ. Funct. Mater., vol. 2, no. 2, pp. 133-141, 2024,https://doi.org/10.1016/j.efmat.2024.01.002
[38] S. A. Mousa, D. A. Wissa, H. H. Hassan, A. A. Ebnalwaled, and S. A. Khairy, "Enhanced photocatalytic activity of green synthesized zinc oxide nanoparticles using low-cost plant extracts," Sci. Rep., vol. 14, no. 1, pp. 1-18, 2024,https://doi.org/10.1038/s41598-024-66975-1
[39] J. P. Shubha et al., "Photocatalytic and eco-emission applications of green synthesized ZnO-CB nanoparticles," J. King Saud Univ. - Sci., vol. 36, no. 9, p. 103373, 2024,https://doi.org/10.1016/j.jksus.2024.103373
[40] S. Singh and B. Jain, "Green Synthesis of Zinc Oxide Nanoparticles Using Aloe Vera: a Study on Optical Properties and Photocatalytic Activity," ORCID:, 2024.https://doi.org/10.26434/chemrxiv-2024-83hjj
[41] N. M. Nemma and Z. S. Sadeq, "Eco-friendly green synthesis and photocatalyst activity of ag-zno nanocomposite," East Eur. J. Phys., pp. 271-278, 2023,https://doi.org/10.26565/2312-4334-2023-3-24
[42] M. H. Kahsay, A. Tadesse, D. Ramadevi, N. Belachew, and K. Basavaiah, "Green synthesis of zinc oxide nanostructures and investigation of their photocatalytic and bactericidal applications," RSC Adv., vol. 9, no. 63, pp. 36967-36981, 2019,https://doi.org/10.1039/C9RA07630A
[43] Tiwari, P.K. et al. 2025. A Review on Wastewater Treatment Using Adsorption and Coagulation/Flocculation Methods. International Journal of Innovations in Science, Engineering And Management. 4, 2 (May 2025), 130-136.https://doi.org/10.69968/ijisem.2025v4i2130-136
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